Thanks everyone for the quick and helpful responses! ?
I do think that it's a bit too high to just be due to temperature, but a valid point that Voc can be higher in lower [EDIT: initially typed "higher"] temps. Temp was around 30C as it was midday Brisbane and they've been sitting in the sun before picking up so they probably were even hotter. So yeah that's why I thought 55V is a bit too high but that was a panel that was cracked throughout. Others are much better but I haven't gotten around to measuring them.
I will probably start with just one, then a 2 panel string, to make sure I won't go over 100V max. I'm then planning to try 2s2p which I think Ecoflow Delta Max should be fine with. I have the blocking diodes and splitters for that as well.
Anyway I will measure the other panels tomorrow and see what the voltage reads! And will try my DMM on a known voltage like my car battery.
I'm curious what happens inside the panel that could lead to a higher than specified voltage, and how bad is it - does this indicate aging or a catastrophic failure?