I am guessing the 4210 is an Epever Tracer therefore it has a 100Voc limit. Do not know the Voc of your panels but for many 100w it is ~22vDC. So yes 3S2P would work with 66Voc.
However the larger proposed battery will be hard to keep charged if you draw it down by any great amount. 400ah at 12vDC is 4800Wh and your 600w system is likely to produce from 1.8kWh up to 3kWh in a sunny day. Even the 230ah if cycled 200ah worth would equal 2.4kWh/day. Likely your PV would get behind and the battery will end up discharged.