There are meters that professional installers will use if there are shading problems on your roof. They sit on your roof and tally up the amount of light received for say a week. If you don't have that problem you can get a rough idea of how much sunlight your roof receives from insolation maps available via google searches. Even a Google search for your area 'average hours of sunlight' will give useful information.
Are you asking from the point of 'is it worth doing this' or 'right, I have panels now am I getting my money's worth' ?