Most seem to be concerned about matching capacity and internal resistance for the cells in battery pack.
IMO that is wrong approach if your concern is long-term pack balance.
What you would need is to match is self-discharge and coulombic efficiency as these are the actual players driving your pack to imbalance.
Both tricky and time-consuming to measure so how about:
A) elevated temperature self-discharge test. A week in 45Cel storage is only something like 1.5% discharge, possibly too tricky to reliably measure?
B) Measuring coulombic efficiency directly is really hard and would need super precision equipment.
But there might be a work-around and it is simply to cycle for multiple times (20? 100?) the series connected pack between 80% and 20% SOC.
After finishing the cycling discharge to 0% to find out which cells drifted farthest from the rest.
IMO that is wrong approach if your concern is long-term pack balance.
What you would need is to match is self-discharge and coulombic efficiency as these are the actual players driving your pack to imbalance.
Both tricky and time-consuming to measure so how about:
A) elevated temperature self-discharge test. A week in 45Cel storage is only something like 1.5% discharge, possibly too tricky to reliably measure?
B) Measuring coulombic efficiency directly is really hard and would need super precision equipment.
But there might be a work-around and it is simply to cycle for multiple times (20? 100?) the series connected pack between 80% and 20% SOC.
After finishing the cycling discharge to 0% to find out which cells drifted farthest from the rest.