No, just used 100 AH as example because it matches % easily.
65 amps for 4 hours is 260 AH consumed, assuming air conditioner runs continuously for the four hours of time. Duty cycle will depend on room size and climate temp.
Taking 260 AH. For LiFePO4 would need 260AH/70% = 371 AH rated battery capacity. For LiFePO4, 100 AH, like BattleBorn, need total of eight batteries. Two in series gives 24v 100 AH, times four for 400 AH total capacity, total of eight 12v, 100 AH batteries. About $8,000 for BattleBorn.
If individual LiFePO4 cells, it takes eight in series to make a 24v system. So if using 280 AH cells would need 8 series by two strings in parallel, 16 total individual 280 AH cells giving 560 AH of total capacity.
Until you get some experience with care and feeding of LiFePO4 batteries I would not recommend building with individual cells as if you screw up it can be a very expensive learning exercise.