Use at least -15C.
VOC is the max voltage that can be supplied to the SCC before magic smoke appears.
The operating range is the voltage the MPPT will operate. This can be a problem as your MPPT is rated for max operating voltage of 115V. With 3S, you are over that voltage. It might work or it might not. It might read the voltage and not turn on.
I'm not a fan of running anything electrical at limits. I see enough electrical failures in my line of work, I don't need to fix my own stuff.
Correct.
Spend money once and be done with it. If you plan on any expansion down the road, be sure to size something like an EGC for any added expansion.
Bump your conduit size up. Have you ran your wire size and number thru a conduit fill calculator? 6 AWG is pretty big. If you want to add another string with 2 more wires in 1"SCH80 PVC conduit will exceed conduit fill according to NEC plus might be a bitch to pull.
If it was me, for what the 6AWG will cost, I'd go buy a higher voltage MPPT, use 10AWG and minimum of 1.25" conduit. Using 1" SCH 80 PVC will allow eleven 10AWG wires down the road. But 1.25" is much easier to pull. (plus up to twenty one 10AWG wires will meet NEC)
6AWG will cost twice what 10AWG will cost. I come up with $234 for 200 feet of 6AWG THHN/THWN plus you need a larger ground if you start paralleling strings. 200 feet of 10AWG THHN/THWN $102, however you would do better buying a 500 foot roll of 10AWG for $140 and a roll of red electrical tape or red heatshrink. That way you can run a few extra wires in the conduit for expansion.
You do have another choice and that is to combine strings right before the SCC. This allows running 10AWG for the 80 feet with less voltage drop and power loss. With just 2 strings you won't need the combiner box, just a disconnect such as the IMO, then combine both strings at the MPPT. No fuses/breakers needed but I would recommend a SPD on each string somewhere. This is your best option if you want to combine strings.
EGC to the battery case