A good rule of thumb for any system is array
Vmp > 1.5X system voltage, so for 24V, you need at least 36
Vmp. The reason you want to shoot higher than peak voltage for Vmp is solar cells get very hot, and that heat reduces their operating voltage, so you need additional voltage margin to ensure you can get to peak battery voltage.
Panel Voc is about 25 higher than Vmp. Voc is what you use to make sure you don't blow up your controller. Easiest way is with the NEC table:
View attachment 219171
If your record low is 0°F, you multiply the array STC Voc by 1.18, and that's your temperature adjusted Voc. That value MUST be under the Voc limits of the controller.
No. Trying to target SoC based on voltage is nearly impossible.
36V
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Pretty much. If you acquired 2X 100W panels from amazon, those tend to be "12V" panels with a Vmp in the 17-20V range, so two in series would get you there (I wouldn't sweat 34 vs. 36V in this example).
They do, pretty much perfectly. You can't get hung up on the slight voltage differences. LFP are essentially "drop-in" replacements for lead acid with a few additional needs that should be met by the LFP BMS.
Yes, that would work, but it would likely take forever to get the second battery charged. It would be far more practical to move the charger to the other battery
Charge voltages aren't mandatory, and they can be problematic if set too high. 14.6/29.2V are likely to trigger over voltage protection due to a single cell being out of balance. It's often easier to pick a lower absorption voltage and run for longer. You can get fully charged at 13.8V/27.6V with a 2 hour absorption in most cases.
If charging with a generator, you want to go for the higher voltages for more efficient generator use. If you're charging from solar, and you have the time, the lower voltage may be more practical/convenient.